Synthesis of Lignin–Urea Formaldehyde (LUF) Wood Adhesive Based on Lignin Extracted from Oil Palm Empty Fruit Bunches (EFB)
DOI:
https://doi.org/10.19109/ccj7gm39Keywords:
Palm Oil, lignin, wood adhesives, LUFAbstract
Oil palm empty fruit bunches are one of the underutilized plantation wastes. Lignin is one of the components of plant cell walls besides cellulose and hemicellulose that can be used as a raw material for the synthesis of lignin-based adhesives, namely lignin-urea-formaldehyde (LUF) adhesive resins. The polymerization reaction of LUF formation was confirmed from the shift and change in the FTIR wavenumber of the -CO-ether group of LUF compared to UF and LF obtained during the synthesis process. The tensile strength test results of all adhesives produced exceeded the tensile strength value of commercial UF adhesives, and it was found that increasing the lignin concentration in the synthesized adhesives was directly proportional to the tensile strength value. Increasing the lignin concentration was also able to reduce formaldehyde emissions from all variations of adhesives produced, but was unable to exceed the lower formaldehyde emission value of UF adhesives.
References
Badan Pusat Statistik, Statistik Kelapa Sawit Indonesia 2023, vol. 17. Jakarta: BPS, 2024.
R. Nabila et al., “Oil palm biomass in Indonesia: Thermochemical upgrading and its utilization,” Apr. 01, 2023, Elsevier Ltd. doi: 10.1016/j.rser.2023.113193.
O. B. Abogunrin-Olafisoye, O. Adeyi, A. J. Adeyi, and E. O. Oke, “Sustainable utilization of oil palm residues and waste in nigeria: practices, prospects, and environmental considerations,” Apr. 01, 2024, Elsevier B.V. doi: 10.1016/j.wmb.2024.01.011.
T. Waluyo, M. Anggraini, and L. Dwi Putri, “The Shear Strength of Clay Stabilized with Palm Bunch Ash and Cement,” Civilla : Jurnal Teknik Sipil Universitas Islam Lamongan, vol. 8, no. 2, pp. 215–222, Oct. 2023, doi: 10.30736/cvl.v8i2.1139.
Y. F. Arifin, M. Arsyad, R. Siswanto, I. K. T. F. Astawa, M. H. Ridha, and M. R. Ramadhani, “TENSILE STRENGTH AND DURABILITY OF OIL PALM EMPTY FRUIT BUNCH FIBER IN SOFT SOIL,” International Journal of GEOMATE, vol. 23, no. 99, pp. 72–81, 2022, doi: 10.21660/2022.99.3610.
S. Susi, M. Ainuri, W. Wagiman, and M. A. F. Falah, “High-Yield Alpha-Cellulose from Oil Palm Empty Fruit Bunches by Optimizing Thermochemical Delignification Processes for Use as Microcrystalline Cellulose,” Int J Biomater, vol. 2023, 2023, doi: 10.1155/2023/9169431.
M. Mahardika et al., “Recent Developments in Oil Palm Empty Fruit Bunch (OPEFB) Fiber Composite,” 2024, Taylor and Francis Ltd. doi: 10.1080/15440478.2024.2309915.
H. Setiawan et al., “Optimized supply chain of empty fruit bunches as feedstocks for second generation bioethanol production,” Case Studies in Chemical and Environmental Engineering, vol. 10, Dec. 2024, doi: 10.1016/j.cscee.2024.100950.
J. Chrobak, J. Iłowska, and A. Chrobok, “Formaldehyde-Free Resins for the Wood-Based Panel Industry: Alternatives to Formaldehyde and Novel Hardeners,” Aug. 01, 2022, MDPI. doi: 10.3390/molecules27154862.
G. Yang, Z. Gong, X. Luo, L. Chen, and L. Shuai, “Bonding wood with uncondensed lignins as adhesives,” Nature, vol. 621, no. 7979, pp. 511–515, Sep. 2023, doi: 10.1038/s41586-023-06507-5.
S. Gürsoy and N. Ayrilmis, “Effect of Lignin Modification of Recycled and Fresh Wood Fibers on Physical, Mechanical, and Thermal Properties of Fiberboard,” Forests, vol. 14, no. 10, Oct. 2023, doi: 10.3390/f14102007.
H. Younesi-Kordkheili, “Reduction of formaldehyde emission from urea-formaldehyde resin by maleated nanolignin,” Int J Adhes Adhes, vol. 132, p. 103677, Jun. 2024, doi: 10.1016/j.ijadhadh.2024.103677.
B. Podkościelna, K. Wnuczek, M. Goliszek, T. Klepka, and K. Dziuba, “Flammability Tests and Investigations of Properties of Lignin-Containing Polymer Composites Based on Acrylates,” Molecules, vol. 25, no. 24, Dec. 2020, doi: 10.3390/MOLECULES25245947.
V. Hemmilä, R. Hosseinpourpia, S. Adamopoulos, and A. Eceiza, “Characterization of Wood-based Industrial Biorefinery Lignosulfonates and Supercritical Water Hydrolysis Lignin,” Waste Biomass Valorization, vol. 11, no. 11, pp. 5835–5845, Nov. 2020, doi: 10.1007/s12649-019-00878-5.
S. Gonçalves, J. Martins, N. T. Paiva, D. Paiva, L. H. Carvalho, and F. D. Magalhães, “The Potential of Visible Spectroscopy as a Tool for the In-Line Monitoring of Lignin Methylolation,” Polymers (Basel), vol. 15, no. 1, Jan. 2023, doi: 10.3390/polym15010178.
S. Bhagia et al., “Nanoscale FTIR and Mechanical Mapping of Plant Cell Walls for Understanding Biomass Deconstruction,” ACS Sustain Chem Eng, vol. 10, no. 9, pp. 3016–3026, Mar. 2022, doi: 10.1021/acssuschemeng.1c08163.
S. Bhattacharyya, L. Matsakas, U. Rova, and P. Christakopoulos, “Melt stable functionalized organosolv and kraft lignin thermoplastic,” Processes, vol. 8, no. 9, Sep. 2020, doi: 10.3390/pr8091108.
X. Yue, Z. Li, S. S. Lam, W.-X. Peng, and Y. He, “Reuse of Cornus officinalis nutlet for bioenergy,” Bioresources, vol. 17, no. 4, pp. 6411–6444, Sep. 2022, doi: 10.15376/biores.17.4.6411-6444.
K. K. Barakoti, P. Subedi, F. Chalyavi, S. Gutierrez-Portocarrero, M. J. Tucker, and M. A. Alpuche-Aviles, “Formaldehyde Analysis in Non-Aqueous Methanol Solutions by Infrared Spectroscopy and Electrospray Ionization,” Front Chem, vol. 9, Jul. 2021, doi: 10.3389/fchem.2021.678112.
H.-Y. Jian, C.-T. Yang, and L.-K. Chu, “Gaseous infrared spectra of the simplest geminal diol CH 2 (OH) 2 and the isotopic analogues in the hydration of formaldehyde,” Physical Chemistry Chemical Physics, vol. 23, no. 27, pp. 14699–14705, 2021, doi: 10.1039/D1CP01354H.
R. Seidl, S. Weiss, R. W. Kessler, W. Kessler, E. M. Zikulnig-Rusch, and A. Kandelbauer, “Prediction of residual curing capacity of melamine-formaldehyde resins at an early stage of synthesis by in-line ftir spectroscopy,” Polymers (Basel), vol. 13, no. 15, Aug. 2021, doi: 10.3390/polym13152541.
Z. Morávková, J. Podešva, V. Shabikova, S. Abbrent, and M. Dušková-Smrčková, “Hydrogen Bonding of Trialkyl-Substituted Urea in Organic Environment,” Molecules, vol. 30, no. 7, Apr. 2025, doi: 10.3390/molecules30071410.
E. Tan, N. Binti Julmohammad, W. Y. Koh, M. S. Abdullah Sani, and B. Rasti, “Application of ATR-FTIR Incorporated with Multivariate Data Analysis for Discrimination and Quantification of Urea as an Adulterant in UHT Milk,” Foods, vol. 12, no. 15, Aug. 2023, doi: 10.3390/foods12152855.
A. Dorieh, F. Pahlavan, K. Hájková, Š. Hýsek, M. Farajollah Pour, and E. H. Fini, “Advancing Sustainable Building Materials: Reducing Formaldehyde Emissions in Medium Density Fiber Boards with Lignin Nanoparticles,” Adv Sustain Syst, vol. 8, no. 9, Sep. 2024, doi: 10.1002/adsu.202400102.
D. Li et al., “Melamine–Urea–Formaldehyde Resin Adhesive Modified with Recycling Lignin: Preparation, Structures and Properties,” Forests, vol. 14, no. 8, Aug. 2023, doi: 10.3390/f14081625.
M. Fazeli et al., “Lignin beyond the status quo : recent and emerging composite applications,” Green Chemistry, vol. 26, no. 2, pp. 593–630, 2024, doi: 10.1039/D3GC03154C.
M. Altgen et al., “Chemical imaging to reveal the resin distribution in impregnation-treated wood at different spatial scales,” Mater Des, vol. 225, Jan. 2023, doi: 10.1016/j.matdes.2022.111481.
T. Zhang, Y. Hu, Y. Dong, S. Jiang, and X. Han, “The Influence of Hydrogen Bonding in Wood and Its Modification Methods: A Review,” Polymers (Basel), vol. 17, no. 15, p. 2064, Jul. 2025, doi: 10.3390/polym17152064.
T. Meng et al., “In Situ Lignin Adhesion for High-Performance Bamboo Composites,” Nano Lett, vol. 23, no. 18, pp. 8411–8418, Sep. 2023, doi: 10.1021/acs.nanolett.3c01497.
Y. Ma et al., “Biodegradable Films Prepared from Pulp Lignocellulose Adhesives of Urea Formaldehyde Resin Modified by Biosulfonate,” Polymers (Basel), vol. 14, no. 14, Jul. 2022, doi: 10.3390/polym14142863.
J. Karthäuser, V. Biziks, C. Mai, and H. Militz, “Lignin and lignin-derived compounds for wood applications—A review,” 2021, MDPI AG. doi: 10.3390/molecules26092533.
Downloads
Published
Issue
Section
License
Copyright (c) 2026 Dian Wardana, Eddiyanto, Nurfajriani, Dwi Sapri Ramadhan, Wulan Dwi Safitri, Jam'an Fahmi

This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.
- The author saves the copyright and gives the journal simultaneously with the license under Creative Commons Attribution License which permits other people to share the work by stating that it is firstly published in this journal.
- The author can post their work in an institutional repository or publish it in a book by by stating that it is firstly published in this journal.
- The author is allowed to post their work online (for instance, in an institutional repository or their own website) before and during the process of delivery. (see Open Access Effect).






.png)



