Enhancing Dye Wastewater Treatment: A Review of Organometallic-Based Adsorption, Photocatalysis and Chemical Degradation

Authors

  • Tety Wahyuningsih Manurung Universitas Palangka Raya
  • Arini Eka Jaya Prastiti Universitas Palangka Raya
  • Caroline Berlisnora Dasilva Universitas Palangka Raya
  • Riskita Putri Universitas Palangka Raya
  • Rusliananur Hairiah Universitas Palangka Raya
  • Rendy Muhamad Iqbal Universiti Teknologi Malaysia
  • Verry Andre Fabiani Universitas Bangka Belitung
  • Marvin Horale Pasaribu Universitas Palangka Raya

DOI:

https://doi.org/10.19109/x1qxs994

Keywords:

dye waste, organometallic compounds, adsorbentss, photodegradation catalyst

Abstract

Dye waste is difficult to remove using conventional methods due to its high stability and resistance to biodegradation. However, scientific advancements have introduced alternative approaches, such as organometallic compounds, which can serve as catalysts and adsorbents. These compounds, particularly metal-organic frameworks (MOFs), possess a large surface area, flexible structure, high crystallinity, and adjustable pore size, making them highly effective in adsorption and photodegradation processes for dye wastewater treatment. This review discusses organometallic compounds, including Materials of Institut Lavoisier (MIL), Zeolitic Imidazolate Frameworks (ZIFs), and Porous Coordination Networks (PCNs), which have proven effective in absorbing certain dyes from water solutions. These MOFs, either alone or in composites with metal oxides, can significantly reduce dye contaminants in water. This review provides an in-depth exploration of the characteristics of organometallic compounds and analyzes their potential as adsorbents and photodegradation catalysts for the removal of dye contaminants from wastewater. Radicals produced through reactions between the valence and conduction bands of the catalyst material with H2O2 can oxidize dye pollutants. This review offers deep insights into the potential of organometallic compounds in dye wastewater treatment.

References

I. Marzouk Trifi, B. Trifi, E. Ben Souissi, and B. Hamrouni, “Response surface methodology for dyes removal by adsorption onto alginate calcium,” Environ Technol, vol. 41, no. 26, pp. 3473–3482, Nov. 2020, doi: 10.1080/09593330.2019.1612470.

K. S. Abou-Melha et al., “Preparation of CuO nanoparticles via organometallic chelate for the removal of acid red 57 from aqueous solutions,” Desalination Water Treat, vol. 222, pp. 282–294, May 2021, doi: 10.5004/dwt.2021.27067.

A. W. Rahmawati, Jumaeri, and T. Sulistyaningsih, “Zeolit Alam Termodifikasi Surfaktan Heksadesiltrimetilammonium (HDTMA) dan Pemanfaatannya sebagai Adsorben Zat Warna Congo Red,” J. Chem. Sci, vol. 7, no. 2, 2018, [Online]. Available: http://journal.unnes.ac.id/sju/index.php/ijcs

M. Said, H. P. Utami, and F. Hayati, “Insertion of bentonite with Organometallic [Fe 3 O(OOC 6 H 5 ) 6 (H 2 O) 3 (NO 3 ).nH 2 O] as Adsorbent of Congo Red,” IOP Conf Ser Mater Sci Eng, vol. 299, p. 012086, Jan. 2018, doi: 10.1088/1757-899X/299/1/012086.

M. Safaei, M. M. Foroughi, N. Ebrahimpoor, S. Jahani, A. Omidi, and M. Khatami, “A review on metal-organic frameworks: Synthesis and applications,” TrAC Trends in Analytical Chemistry, vol. 118, pp. 401–425, Sep. 2019, doi: 10.1016/j.trac.2019.06.007.

V. F. Yusuf, N. I. Malek, and S. K. Kailasa, “Review on Metal–Organic Framework Classification, Synthetic Approaches, and Influencing Factors: Applications in Energy, Drug Delivery, and Wastewater Treatment,” ACS Omega, vol. 7, no. 49, pp. 44507–44531, Dec. 2022, doi: 10.1021/acsomega.2c05310.

M. Beydaghdari, F. Hooriabad Saboor, A. Babapoor, V. Karve, and M. Asgari, “Recent Advances in MOF-Based Adsorbents for Dye Removal from the Aquatic Environment,” Energies (Basel), vol. 15, no. 6, p. 2023, Mar. 2022, doi: 10.3390/en15062023.

M. G. V. Wee, A. Chinnappan, and S. Ramakrishna, “Elucidating Improvements to MIL‐101(Cr)’s Porosity and Particle Size Distributions based on Innovations and Fine‐Tuning in Synthesis Procedures,” Adv Mater Interfaces, vol. 10, no. 18, Jun. 2023, doi: 10.1002/admi.202300065.

P. Tong, J. Liang, X. Jiang, and J. Li, “Research Progress on Metal-Organic Framework Composites in Chemical Sensors,” Crit Rev Anal Chem, vol. 50, no. 4, pp. 376–392, Jul. 2020, doi: 10.1080/10408347.2019.1642732.

J. Zhang et al., “High performance humidity sensor based on metal organic framework MIL-101(Cr) nanoparticles,” J Alloys Compd, vol. 695, pp. 520–525, Feb. 2017, doi: 10.1016/j.jallcom.2016.11.129.

Z. Mohammadifard, R. Saboori, N. S. Mirbagheri, and S. Sabbaghi, “Heterogeneous photo-Fenton degradation of formaldehyde using MIL-100(Fe) under visible light irradiation,” Environmental Pollution, vol. 251, pp. 783–791, Aug. 2019, doi: 10.1016/j.envpol.2019.04.143.

J. Shin et al., “MIL-101(Fe) as a lithium-ion battery electrode material: a relaxation and intercalation mechanism during lithium insertion,” J Mater Chem A Mater, vol. 3, no. 8, pp. 4738–4744, 2015, doi: 10.1039/C4TA06694D.

X. Hou et al., “Removal of antibiotic tetracycline by metal-organic framework MIL-101(Cr) loaded nano zero-valent iron,” J Mol Liq, vol. 313, p. 113512, Sep. 2020, doi: 10.1016/j.molliq.2020.113512.

P. A. P. Mendes et al., “Separation of Hexane Isomers on Rigid Porous Metal Carboxylate-Based Metal—Organic Frameworks,” Adsorption Science & Technology, vol. 32, no. 6, pp. 475–488, Jun. 2014, doi: 10.1260/0263-6174.32.6.475.

B. Rungtaweevoranit, C. S. Diercks, M. J. Kalmutzki, and O. M. Yaghi, “Spiers Memorial Lecture: : Progress and prospects of reticular chemistry,” Faraday Discuss, vol. 201, pp. 9–45, 2017, doi: 10.1039/C7FD00160F.

K.-Y. A. Lin and H.-A. Chang, “Ultra-high adsorption capacity of zeolitic imidazole framework-67 (ZIF-67) for removal of malachite green from water,” Chemosphere, vol. 139, pp. 624–631, Nov. 2015, doi: 10.1016/j.chemosphere.2015.01.041.

H. Li et al., “Enhanced adsorptive removal of anionic and cationic dyes from single or mixed dye solutions using MOF PCN-222,” RSC Adv, vol. 7, no. 27, pp. 16273–16281, 2017, doi: 10.1039/C7RA01647F.

J. Huang, X. Zhang, H. Song, C. Chen, F. Han, and C. Wen, “Protonated graphitic carbon nitride coated metal-organic frameworks with enhanced visible-light photocatalytic activity for contaminants degradation,” Appl Surf Sci, vol. 441, pp. 85–98, May 2018, doi: 10.1016/j.apsusc.2018.02.027.

Y.-S. Wei, M. Zhang, R. Zou, and Q. Xu, “Metal–Organic Framework-Based Catalysts with Single Metal Sites,” Chem Rev, vol. 120, no. 21, pp. 12089–12174, Nov. 2020, doi: 10.1021/acs.chemrev.9b00757.

Z. U. Zango et al., “A Critical Review on Metal-Organic Frameworks and Their Composites as Advanced Materials for Adsorption and Photocatalytic Degradation of Emerging Organic Pollutants from Wastewater,” Polymers (Basel), vol. 12, no. 11, p. 2648, Nov. 2020, doi: 10.3390/polym12112648.

L. Fu et al., “Post-functionalization of UiO-66-NH2 by 2,5-Dimercapto-1,3,4-thiadiazole for the high efficient removal of Hg(II) in water,” J Hazard Mater, vol. 368, pp. 42–51, Apr. 2019, doi: 10.1016/j.jhazmat.2019.01.025.

J. Bedia, M. Peñas-Garzón, A. Gómez-Avilés, J. J. Rodriguez, and C. Belver, “A Review on the Synthesis and Characterization of Biomass-Derived Carbons for Adsorption of Emerging Contaminants from Water,” C (Basel), vol. 4, no. 4, p. 63, Nov. 2018, doi: 10.3390/c4040063.

M. Tong, D. Liu, Q. Yang, S. Devautour-Vinot, G. Maurin, and C. Zhong, “Influence of framework metal ions on the dye capture behavior of MIL-100 (Fe, Cr) MOF type solids,” J Mater Chem A Mater, vol. 1, no. 30, pp. 8534–8537, Aug. 2013, doi: 10.1039/c3ta11807j.

H. Li et al., “Enhanced adsorptive removal of anionic and cationic dyes from single or mixed dye solutions using MOF PCN-222,” RSC Adv, vol. 7, no. 27, pp. 16273–16281, 2017, doi: 10.1039/c7ra01647f.

Y. Feng, Y. Li, M. Xu, S. Liu, and J. Yao, “Fast adsorption of methyl blue on zeolitic imidazolate framework-8 and its adsorption mechanism,” RSC Adv, vol. 6, no. 111, pp. 109608–109612, 2016, doi: 10.1039/c6ra23870j.

K. Y. A. Lin and H. A. Chang, “Ultra-high adsorption capacity of zeolitic imidazole framework-67 (ZIF-67) for removal of malachite green from water,” Chemosphere, vol. 139, pp. 624–631, Nov. 2015, doi: 10.1016/j.chemosphere.2015.01.041.

M. Tong, D. Liu, Q. Yang, S. Devautour-Vinot, G. Maurin, and C. Zhong, “Influence of framework metal ions on the dye capture behavior of MIL-100 (Fe, Cr) MOF type solids,” J Mater Chem A Mater, vol. 1, no. 30, p. 8534, 2013, doi: 10.1039/c3ta11807j.

M. H. Pasaribu, K. Karelius, E. P. Ramdhani, R. Agnestisia, Z. Pereiz, and E. P. Toepak, “Synthesis of Mil-100(Fe)@Fe 3 O 4 Composite using Zircon Mining Magnetic Waste as an Adsorbent for Methylene Blue Dye,” BIO Web Conf, vol. 70, p. 02010, Nov. 2023, doi: 10.1051/bioconf/20237002010.

Y. Feng, Y. Li, M. Xu, S. Liu, and J. Yao, “Fast adsorption of methyl blue on zeolitic imidazolate framework-8 and its adsorption mechanism,” RSC Adv, vol. 6, no. 111, pp. 109608–109612, 2016, doi: 10.1039/C6RA23870J.

S. Hariganesh et al., “Facile large scale synthesis of CuCr2O4/CuO nanocomposite using MOF route for photocatalytic degradation of methylene blue and tetracycline under visible light,” Appl Organomet Chem, vol. 34, no. 2, Feb. 2020, doi: 10.1002/aoc.5365.

N. Chang et al., “Regulation of the adsorption affinity of metal-organic framework MIL-101 via a TiO2 coating strategy for high capacity adsorption and efficient photocatalysis,” Microporous and Mesoporous Materials, vol. 266, pp. 47–55, Aug. 2018, doi: 10.1016/j.micromeso.2018.02.051.

J. Huang, X. Zhang, H. Song, C. Chen, F. Han, and C. Wen, “Protonated graphitic carbon nitride coated metal-organic frameworks with enhanced visible-light photocatalytic activity for contaminants degradation,” Appl Surf Sci, vol. 441, pp. 85–98, May 2018, doi: 10.1016/j.apsusc.2018.02.027.

B. Abdollahi, A. Najafidoust, E. Abbasi Asl, and M. Sillanpaa, “Fabrication of ZiF-8 metal organic framework (MOFs)-based CuO-ZnO photocatalyst with enhanced solar-light-driven property for degradation of organic dyes,” Arabian Journal of Chemistry, vol. 14, no. 12, Dec. 2021, doi: 10.1016/j.arabjc.2021.103444.

A. Ayati, M. N. Shahrak, B. Tanhaei, and M. Sillanpää, “Emerging adsorptive removal of azo dye by metal–organic frameworks,” Oct. 01, 2016, Elsevier Ltd. doi: 10.1016/j.chemosphere.2016.06.065.

W. Guan, X. Gao, G. Ji, Y. Xing, C. Du, and Z. Liu, “Fabrication of a magnetic nanocomposite photocatalysts Fe3O4@ZIF-67 for degradation of dyes in water under visible light irradiation,” J Solid State Chem, vol. 255, pp. 150–156, Nov. 2017, doi: 10.1016/j.jssc.2017.08.012.

R. Ediati et al., “Addition of graphene oxide to ZIF-8/HKUST-1 composite for enhanced adsorptive and photocatalytic removal of congo red in wastewater,” S Afr J Chem Eng, vol. 46, pp. 132–142, Oct. 2023, doi: 10.1016/j.sajce.2023.07.006.

N. M. Mahmoodi, J. Abdi, M. Oveisi, M. Alinia Asli, and M. Vossoughi, “Metal-organic framework (MIL-100 (Fe)): Synthesis, detailed photocatalytic dye degradation ability in colored textile wastewater and recycling,” Mater Res Bull, vol. 100, pp. 357–366, Apr. 2018, doi: 10.1016/j.materresbull.2017.12.033.

N. M. Mahmoodi and J. Abdi, “Nanoporous metal-organic framework (MOF-199): Synthesis, characterization and photocatalytic degradation of Basic Blue 41,” Microchemical Journal, vol. 144, pp. 436–442, Jan. 2019, doi: 10.1016/j.microc.2018.09.033.

S. Hariganesh et al., “Facile large scale synthesis of CuCr 2 O 4 /CuO nanocomposite using MOF route for photocatalytic degradation of methylene blue and tetracycline under visible light,” Appl Organomet Chem, vol. 34, no. 2, Feb. 2020, doi: 10.1002/aoc.5365.

N. Chang et al., “Regulation of the adsorption affinity of metal-organic framework MIL-101 via a TiO2 coating strategy for high capacity adsorption and efficient photocatalysis,” Microporous and Mesoporous Materials, vol. 266, pp. 47–55, Aug. 2018, doi: 10.1016/j.micromeso.2018.02.051.

A. Ayati, M. N. Shahrak, B. Tanhaei, and M. Sillanpää, “Emerging adsorptive removal of azo dye by metal–organic frameworks,” Chemosphere, vol. 160, pp. 30–44, Oct. 2016, doi: 10.1016/j.chemosphere.2016.06.065.

W. Guan, X. Gao, G. Ji, Y. Xing, C. Du, and Z. Liu, “Fabrication of a magnetic nanocomposite photocatalysts Fe3O4@ZIF-67 for degradation of dyes in water under visible light irradiation,” J Solid State Chem, vol. 255, pp. 150–156, Nov. 2017, doi: 10.1016/j.jssc.2017.08.012.

R. Ediati et al., “Addition of graphene oxide to ZIF-8/HKUST-1 composite for enhanced adsorptive and photocatalytic removal of congo red in wastewater,” S Afr J Chem Eng, vol. 46, pp. 132–142, Oct. 2023, doi: 10.1016/j.sajce.2023.07.006.

N. M. Mahmoodi, J. Abdi, M. Oveisi, M. Alinia Asli, and M. Vossoughi, “Metal-organic framework (MIL-100 (Fe)): Synthesis, detailed photocatalytic dye degradation ability in colored textile wastewater and recycling,” Mater Res Bull, vol. 100, pp. 357–366, Apr. 2018, doi: 10.1016/j.materresbull.2017.12.033.

N. M. Mahmoodi and J. Abdi, “Nanoporous metal-organic framework (MOF-199): Synthesis, characterization and photocatalytic degradation of Basic Blue 41,” Microchemical Journal, vol. 144, pp. 436–442, Jan. 2019, doi: 10.1016/j.microc.2018.09.033.

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Published

2024-08-31

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How to Cite

Enhancing Dye Wastewater Treatment: A Review of Organometallic-Based Adsorption, Photocatalysis and Chemical Degradation. (2024). ALKIMIA : Jurnal Ilmu Kimia Dan Terapan, 8(2), 23-37. https://doi.org/10.19109/x1qxs994