Evaluation of Syzygium myrtifolium leaves extract as an eco-friendly inhibitor for steel in reinforced concrete

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Muhammad Alwi Syahara

Abstract

Reinforced concrete is a concrete mixture that is reinforced with steel to strengthen the concrete in a building construction. One of the problems with steel is corrosion which can damage the concrete structure. One way to inhibit the corrosion process is to inhibit the corrosion rate using organic/eco-friendly inhibitors. A potential eco-friendly inhibitor is Syzygium myrtifolium leaves. This study aims to determine the corrosion rate and inhibition efficiency in reinforcing steel (BjTP) 280. This research method begins with maceration of Syzygium myrtifolium leaves using 96% alcohol for 96 hours. Then BjTP 280 is immersed in concentrated extract with variations in immersing time of 0 hours, 24 hours, 72 hours, 120 hours, and 168 hours. Furthermore, BjTP 280 is used in K350 quality concrete structures. Calculation of corrosion rate using weight loss method based on ASTM G 31-72, corrosion testing based on ASTM C 876-91 by immersing concrete in 3.5% NaCl corrosive media solution and flowing 6 V DC current for 14 days. The corrosion rate (mm/year) in each variation of immersion in inhibitor decreased, respectively 875.95 (0 hours); 298.66 (24 hours); 99.55 (72 hours); 79.73 (120 hours); 42.66 (168 hours). Meanwhile, the inhibition efficiency value (%) increased successively, namely -% (0 hours); 65,9% (24 hours); 88,63% (72 hours); 90,93% (120 hours); 95,12% (168 hours). The results showed the best corrosion rate reduction of 42.66 mm/year with inhibition efficiency of 95,12% obtained at 168 hours of immersion.

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Evaluation of Syzygium myrtifolium leaves extract as an eco-friendly inhibitor for steel in reinforced concrete. (2025). ALKIMIA : Jurnal Ilmu Kimia Dan Terapan, 7(1). https://doi.org/10.19109/ncgwn334
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How to Cite

Evaluation of Syzygium myrtifolium leaves extract as an eco-friendly inhibitor for steel in reinforced concrete. (2025). ALKIMIA : Jurnal Ilmu Kimia Dan Terapan, 7(1). https://doi.org/10.19109/ncgwn334

References

D. Mardiana, E. Ginting, and A. Riyanto, “Efektivitas Ekstrak Daun Jambu Biji (Psidium Guajava l.) Sebagai Inhibitor Pada Baja Karbon St37 dalam Medium Korosif NaCl 3%,” Journal of Energy, Material, and Instrumentation Technology, vol. 1, no. 3, pp. 119–125, Nov. 2020, doi: 10.23960/JEMIT.V1I3.128.

A. Kuat et al., “Analisa Kuat Lentur Balok Beton Bertulang dengan Menggunakan Profil Baja Ringan sebagai Tulangan,” Teknika Sains: Jurnal Ilmu Teknik, vol. 6, no. 1, pp. 24–34, Aug. 2021, doi: 10.24967/TEKSIS.V6I1.1233.

Sugeng Hendik Purwanto, “Evaluasi Karakteristik Baja Tulangan Beton Di Malang Raya Berdasarkan Standar SNI 2052-2017,” Aptek, vol. 13, no. 2, pp. 59–68, Jul. 2021, doi: 10.30606/APTEK.V13I2.814.

B. Mahardika, “Studi Eksperimen Pengaruh Variasi Inhibitor Dan Konsentrasi Inhibitor Terhadap Laju Korosi Dan Penentuan Efisiensi Inhibisi Pada Baja Tulangan Beton St 42 Di Kondisi Lingkungan Laut,” 2016.

A. (Arini) Nikitasari, M. S. (Moch) Anwar, E. (Efendi) Mabruri, and S. (Sundjono) Sundjono, “Evaluasi Inhibitor Sodium Nitrit di dalam Larutan Beton Sintetis,” Jurnal Sains Materi Indonesia, vol. 16, no. 1, pp. 12–18, 2014, doi: 10.17146/JSMI.2014.16.1.4327.

H. Simanjuntak, E. Ginting, and S. Suprihatin, “Pengaruh Penambahan Inhibitor Ekstrak Kopi Dan Waktu Perendaman Terhadap Laju Korosi Pada Baja Karbon Aisi 1020 Dalam Larutan Nacl 3%,” Jurnal Teori dan Aplikasi Fisika, vol. 07, no. 02, pp. 239–248, Jul. 2019, Accessed: Mar. 05, 2025. [Online]. Available: https://jtaf.fmipa.unila.ac.id/index.php/jtaf/article/view/226

K. A. Roni, E. Elfidiah, E. Yuliwati, and B. Marselia, “PENAMBAHAN INHIBITOR EKSTRAK DAUN PEPAYA (CARICA PAPAYA L.) TERHADAP PENGARUH LAJU KOROSI PADA BAJA KARBON DALAM LARUTAN AIR LAUT,” Jurnal Redoks, vol. 7, no. 1, pp. 28–35, Jul. 2022, doi: 10.31851/REDOKS.V7I1.7005.

N. Al Otaibi and H. H. Hammud, “Corrosion Inhibition Using Harmal Leaf Extract as an Eco-Friendly Corrosion Inhibitor,” Molecules 2021, Vol. 26, Page 7024, vol. 26, no. 22, p. 7024, Nov. 2021, doi: 10.3390/MOLECULES26227024.

S. Abbas Abdulsada, A. I. Al-Mosawi, A. Amer, and A. A. Amer Hadi, “Studying the Effect of Eco-addition Inhibitors on Corrosion Resistance of Reinforced Concrete,” Bioprocess Engineering, vol. 1, no. 3, pp. 81–86, 2017, doi: 10.11648/j.be.20170103.14.

B. Tan et al., “Papaya leaves extract as a novel eco-friendly corrosion inhibitor for Cu in H2SO4 medium,” J Colloid Interface Sci, vol. 582, pp. 918–931, Jan. 2021, doi: 10.1016/J.JCIS.2020.08.093.

S. Harsimi, M. A. Sultan, and M. Y. H. Abbas, “PENGGUNAAN ABU SEKAM PADI SEBAGAI INHIBITOR ALAMI PADA TULANGAN BETON BERTULANG,” JURNAL SIPIL SAINS, vol. 9, no. 2, 2019, doi: 10.33387/SIPILSAINS.V9I18.1308.

M. Ben Harb, S. Abubshait, N. Etteyeb, M. Kamoun, and A. Dhouib, “Olive leaf extract as a green corrosion inhibitor of reinforced concrete contaminated with seawater,” Arabian Journal of Chemistry, vol. 13, no. 3, pp. 4846–4856, Mar. 2020, doi: 10.1016/J.ARABJC.2020.01.016.

N. Barmawi, M. A. Sultan, and M. Y. H. Abbas, “Pengaruh Konsentrasi Ekstrak Daun Tembakau Sebagai Inhibitor Pada Tulangan Beton Bertulang,” Rekayasa Sipil, vol. 15, no. 1, pp. 16–21, Feb. 2021, doi: 10.21776/UB.REKAYASASIPIL.2021.015.01.3.

S. A. Asipita, M. Ismail, M. Z. A. Majid, Z. A. Majid, C. Abdullah, and J. Mirza, “Green Bambusa Arundinacea leaves extract as a sustainable corrosion inhibitor in steel reinforced concrete,” J Clean Prod, vol. 67, pp. 139–146, Mar. 2014, doi: 10.1016/J.JCLEPRO.2013.12.033.

R. H. Kusriani, S. M. Rosandhy, and E. Elfahmi, “Luteolin, a flavonoid from Syzygium myrtifolium Walp.,” Current Research on Biosciences and Biotechnology, vol. 1, no. 1, pp. 31–33, Aug. 2019, doi: 10.5614/CRBB.2019.1.1/FKAN4064.

Elfidiah, D. Kharismadewi, and E. Yuliwati, “Wuluh starfruit (Averrhoa bilimbi linn.) leaves extract as green corrosion inhibitor in reinforced steel,” J Phys Conf Ser, vol. 1444, no. 1, p. 012003, Jan. 2020, doi: 10.1088/1742-6596/1444/1/012003.

I. A. Abro, M. I. Abro, M. E. H. Assad, M. Rahimi-Gorji, and N. M. Hoang, “Investigation and evaluation of neem leaves extract as a green inhibitor for corrosion behavior of mild steel: An experimental study,” https://doi.org/10.1177/0954406220937723, vol. 235, no. 4, pp. 734–743, Jul. 2020, doi: 10.1177/0954406220937723.

H. M. Yang, “Role of Organic and Eco-Friendly Inhibitors on the Corrosion Mitigation of Steel in Acidic Environments—A State-of-Art Review,” Molecules 2021, Vol. 26, Page 3473, vol. 26, no. 11, p. 3473, Jun. 2021, doi: 10.3390/MOLECULES26113473.